Now according to Wikipedia, the Turnbull blue and Prussian blue are the same compound, ie, ferriferrocyanide $\left(\ce{Fe4[Fe(CN)6]3} \right)$. But the book says that Turnbull blue is ferroferricyanide $\left(\ce{Fe3[Fe(CN)6]2}\right)$ which kinda makes sense because we are adding ferricyanide to ferrous solution.. As a result, knowing that CN− is cyanide, the inner sphere iron is Fe3+, since 6 × −1 +3 = −3 for the total anionic charge. Well, hopefully you can see that there are two different iron atoms here. Otherwise, it wouldn't make sense to write the two "Fe" atoms separately like this. If you really meant "Fe"_4 ["Fe" ("CN")_6]_3, Prussian.
![FeCl2 + K3[Fe(CN)6] = KCl + Fe3[Fe(CN)6]2 FeCl2 + K3[Fe(CN)6] = KCl + Fe3[Fe(CN)6]2](https://chemisthunter.com/image_source/ce4dd3e3846257bf5b7b123b12163ef8.png)
FeCl2 + K3[Fe(CN)6] = KCl + Fe3[Fe(CN)6]2
![Гексацианоферрат(3) Цинка Zn3[Fe(CN)6]2. Реакция Гексацианоферрата(3) Калия и Сульфата Цинка Гексацианоферрат(3) Цинка Zn3[Fe(CN)6]2. Реакция Гексацианоферрата(3) Калия и Сульфата Цинка](https://i.ytimg.com/vi/B_wDQrg0GKo/maxresdefault.jpg)
Гексацианоферрат(3) Цинка Zn3[Fe(CN)6]2. Реакция Гексацианоферрата(3) Калия и Сульфата Цинка

How to find the Oxidation Number for Fe in the K3Fe(CN)6 ion. YouTube
![KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎 KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎](https://picx.zhimg.com/50/v2-f3fdafa6e2d7135d376213372a484e46_720w.jpg?source=1940ef5c)
KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎
![Illustration of the K3[Fe(CN)6]/K4[Fe(CN)6] redox probe reactions and... Download Scientific Illustration of the K3[Fe(CN)6]/K4[Fe(CN)6] redox probe reactions and... Download Scientific](https://www.researchgate.net/publication/365306437/figure/fig1/AS:11431281096646536@1668192522856/Illustration-of-the-K3FeCN6-K4FeCN6-redox-probe-reactions-and-resulting.png)
Illustration of the K3[Fe(CN)6]/K4[Fe(CN)6] redox probe reactions and... Download Scientific
![List 93+ Pictures K3[fe(cn)6] Completed List 93+ Pictures K3[fe(cn)6] Completed](https://www.chemtube3d.com/images/gallery/inorganicsjpgs/fecn63-.jpg)
List 93+ Pictures K3[fe(cn)6] Completed
![Chemical Forums Cu3[Fe(CN)6]2 + NaOH Chemical Forums Cu3[Fe(CN)6]2 + NaOH](https://www.chemicalforums.com/proxy.php?request=http:%2F%2Fi.imgur.com%2F2ngpemr.jpg&hash=4a4cdf492e28e348ce1f71aac64732c9b2bf243d)
Chemical Forums Cu3[Fe(CN)6]2 + NaOH
![a) Unit cell of K 2 Zn 3 [Fe(CN) 6 ] 2. and b) unit cell of Na 2 Zn 3... Download Scientific a) Unit cell of K 2 Zn 3 [Fe(CN) 6 ] 2. and b) unit cell of Na 2 Zn 3... Download Scientific](https://www.researchgate.net/publication/329434073/figure/fig6/AS:700647435423744@1544058774432/a-Unit-cell-of-K-2-Zn-3-FeCN-6-2-and-b-unit-cell-of-Na-2-Zn-3-FeCN-6-2.jpg)
a) Unit cell of K 2 Zn 3 [Fe(CN) 6 ] 2. and b) unit cell of Na 2 Zn 3... Download Scientific
![KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎 KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎](https://pic1.zhimg.com/50/v2-6f8faf7824ffe1d7921f7a2a03a6c29c_720w.jpg?source=1940ef5c)
KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎
![FeSO4 + K3[Fe(CN)6] = K2SO4 + Fe3[Fe(CN)6]2 FeSO4 + K3[Fe(CN)6] = K2SO4 + Fe3[Fe(CN)6]2](https://chemisthunter.com/image_source/2364c5af13a313571149794ccc1fa238.png)
FeSO4 + K3[Fe(CN)6] = K2SO4 + Fe3[Fe(CN)6]2

Electron Configuration for Fe, Fe2+, and Fe3+ (Iron and Iron Ions) YouTube
![Fe4鉄(Ⅲ)イオンとヘキサシアノ鉄(Ⅲ)酸イオンの反応Fe3+ + [Fe(CN)6]3.MTS YouTube Fe4鉄(Ⅲ)イオンとヘキサシアノ鉄(Ⅲ)酸イオンの反応Fe3+ + [Fe(CN)6]3.MTS YouTube](https://i.ytimg.com/vi/lg5b7A1fqoU/maxresdefault.jpg)
Fe4鉄(Ⅲ)イオンとヘキサシアノ鉄(Ⅲ)酸イオンの反応Fe3+ + [Fe(CN)6]3.MTS YouTube
![Left Proposed structure for [Ni(AEAPTS) 2 ] 3 [Fe(CN) 6 ] 2 . The... Download Scientific Diagram Left Proposed structure for [Ni(AEAPTS) 2 ] 3 [Fe(CN) 6 ] 2 . The... Download Scientific Diagram](https://www.researchgate.net/publication/329534064/figure/fig3/AS:865210667655168@1583293706202/Left-Proposed-structure-for-NiAEAPTS-2-3-FeCN-6-2-The-cyanometallates-are_Q640.jpg)
Left Proposed structure for [Ni(AEAPTS) 2 ] 3 [Fe(CN) 6 ] 2 . The... Download Scientific Diagram
![Fe3鉄(Ⅱ)イオンとヘキサシアノ鉄(Ⅱ)酸イオンFe2+ + [Fe(CN)6]4 ferrous ion.MTS YouTube Fe3鉄(Ⅱ)イオンとヘキサシアノ鉄(Ⅱ)酸イオンFe2+ + [Fe(CN)6]4 ferrous ion.MTS YouTube](https://i.ytimg.com/vi/hidKwysJVWI/maxresdefault.jpg)
Fe3鉄(Ⅱ)イオンとヘキサシアノ鉄(Ⅱ)酸イオンFe2+ + [Fe(CN)6]4 ferrous ion.MTS YouTube
![Crystal structure of (a) Fe[Fe(CN) 6 ] and (b) Na 2 Fe[Fe(CN) 6 ]. Download Scientific Diagram Crystal structure of (a) Fe[Fe(CN) 6 ] and (b) Na 2 Fe[Fe(CN) 6 ]. Download Scientific Diagram](https://www.researchgate.net/profile/Fadhlul-Wafi-Badrudin-2/publication/341108689/figure/fig4/AS:923545098006530@1597201718467/Charge-density-diagram-of-FeFeCN-6_Q640.jpg)
Crystal structure of (a) Fe[Fe(CN) 6 ] and (b) Na 2 Fe[Fe(CN) 6 ]. Download Scientific Diagram
![KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎 KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎](https://picx.zhimg.com/v2-1875ad73295e3c175dcc5b6b030b00ea_r.jpg?source=1940ef5c)
KFe[Fe(CN)6]和Fe3[Fe(CN)6]2有什么区别? 知乎
![The hybridization of Fe in K_3[Fe(CN)_6] is The hybridization of Fe in K_3[Fe(CN)_6] is](https://haygot.s3.amazonaws.com/questions/1575020_1730098_ans_dbd888825d9c4a4393637ee2b080a89f.jpg)
The hybridization of Fe in K_3[Fe(CN)_6] is
![Proposed mechanism of the interaction between [Fe(CN) 6 ] 3/4and gold... Download Scientific Proposed mechanism of the interaction between [Fe(CN) 6 ] 3/4and gold... Download Scientific](https://www.researchgate.net/publication/332943801/figure/fig4/AS:756278771056642@1557322318877/Proposed-mechanism-of-the-interaction-between-FeCN-6-3-4-and-gold-electrode-b-1-and.jpg)
Proposed mechanism of the interaction between [Fe(CN) 6 ] 3/4and gold... Download Scientific
![Fe2鉄(Ⅲ)イオンとヘキサシアノ鉄(Ⅱ)酸イオンFe3+ + Fe(CN)6]4 ferric ion.MTS YouTube Fe2鉄(Ⅲ)イオンとヘキサシアノ鉄(Ⅱ)酸イオンFe3+ + Fe(CN)6]4 ferric ion.MTS YouTube](https://i.ytimg.com/vi/1VoTCSO701U/maxresdefault.jpg)
Fe2鉄(Ⅲ)イオンとヘキサシアノ鉄(Ⅱ)酸イオンFe3+ + Fe(CN)6]4 ferric ion.MTS YouTube

Fe^2+ ,Fe^3+ and Fe Electron Configuration (Two Ways)Crash Course Chemistry YouTube
The Iron One-Pot Reaction. Complex-formation and oxidation/reduction chemsitry of iron. The following solutions are added to a beaker containing 0.10M FeSO 4 solution. Solution: Chemical Equation: Observations: Sodium Citrate. Fe 2+ (aq) + C 6 H 5 O 7 3- (aq) <=> Fe (C 6 H 5 O 7) - (aq) A light yellow complex forms.. Fe(CN) 6 3H 2 O] and potassium ferricyanide [K 3 Fe(CN) 6] complexes are used in this experiment. The cyano group in each complex has a charge of -1 and potassium has a charge of +1. Thus, the complex ferrocyanide, Fe(CN) 6 4-, contains iron in the +2 oxidation state while the complex ferricyanide, Fe(CN) 6 3-, contains iron in the +3.